Rizzuto, F. J., von Krbek, L. K. S. & Nitschke, J. R. Strategies for binding multiple guests in metal–organic cages. Nat. Rev. Chem. 3, 204–222 (2019).
Gramage-Doria, R. et al. Gold(I) catalysis at extreme concentrations inside self-assembled nanospheres. Angew. Chem. Int. Ed. Engl. 53, 13380–13384 (2014).
Article CAS PubMed Google Scholar
Jongkind, L. J., Elemans, J. A. A. W. & Reek, J. N. H. Cofactor controlled encapsulation of a rhodium hydroformylation catalyst. Angew. Chem. Int. Ed. Engl. 58, 2696–2699 (2019).
Article CAS PubMed PubMed Central Google Scholar
Aida, T., Meijer, E. W. & Stupp, S. I. Functional supramolecular polymers. Science 335, 813–817 (2012).
Article CAS PubMed PubMed Central Google Scholar
Dydio, P., Dzik, W. I., Lutz, M., de Bruin, B. & Reek, J. N. H. Remote supramolecular control of catalyst selectivity in the hydroformylation of alkenes. Angew. Chem. Int. Ed. Engl. 50, 396–400 (2011).
Article CAS PubMed Google Scholar
Yoshioka, S., Inokuma, Y., Hoshino, M., Sato, T. & Fujita, M. Absolute structure determination of compounds with axial and planar chirality using the crystalline sponge method. Chem. Sci. 6, 3765–3768 (2015).
Article CAS PubMed PubMed Central Google Scholar
Cordier, P., Tournilhac, F., Soulié-Ziakovic, C. & Leibler, L. Self-healing and thermoreversible rubber from supramolecular assembly. Nature 451, 977–980 (2008).
Article CAS PubMed Google Scholar
Sepehrpour, H., Fu, W., Sun, Y. & Stang, P. J. Biomedically relevant self-assembled metallacycles and metallacages. J. Am. Chem. Soc. 141, 14005–14020 (2019).
Article CAS PubMed PubMed Central Google Scholar
Dankers, P. Y. W. et al. The use of fibrous, supramolecular membranes and human tubular cells for renal epithelial tissue engineering: towards a suitable membrane for a bioartificial kidney. Macromol. Biosci. 10, 1345–1354 (2010).
Article CAS PubMed Google Scholar
Anelli, P. L. et al. Molecular meccano. 1. [2]Rotaxanes and a [2]catenane made to order. J. Am. Chem. Soc. 114, 193–218 (1992).
Bols, P. S. & Anderson, H. L. Template-directed synthesis of molecular nanorings and cages. Acc. Chem. Res. 51, 2083–2092 (2018).
Article CAS PubMed Google Scholar
Fuller, A.-M. L., Leigh, D. A. & Lusby, P. J. One template, multiple rings: controlled iterative addition of macrocycles onto a single binding site rotaxane thread. Angew. Chem. Int. Ed. Engl. 46, 5015–5019 (2007).
Article CAS PubMed Google Scholar
Meng, W. et al. A self-assembled M8L6 cubic cage that selectively encapsulates large aromatic guests. Angew. Chem. Int. Ed. Engl. 50, 3479–3483 (2011).
Article CAS PubMed Google Scholar
Yoshizawa, M., Klosterman, J. K. & Fujita, M. Functional molecular flasks: new properties and reactions within discrete, self-assembled hosts. Angew. Chem. Int. Ed. Engl. 48, 3418–3438 (2009).
Article CAS PubMed Google Scholar
Sun, Q.-F., Murase, T., Sato, S. & Fujita, M. A sphere-in-sphere complex by orthogonal self-assembly. Angew. Chem. Int. Ed. Engl. 50, 10318–10321 (2011).
Article CAS PubMed Google Scholar
Clever, G. H. & Punt, P. Cation–anion arrangement patterns in self-assembled Pd2L4 and Pd4L8 coordination cages. Acc. Chem. Res. 50, 2233–2243 (2017).
Article CAS PubMed Google Scholar
Rao, S.-J., Zhang, Q., Ye, X.-H., Gao, C. & Qu, D.-H. Integrative self-sorting: one-pot synthesis of a hetero[4]rotaxane from a daisy-chain-containing hetero[4]pseudorotaxane. Chem. Asian J. 13, 815–821 (2018).
Article CAS PubMed Google Scholar
He, Z., Jiang, W. & Schalley, C. A. Integrative self-sorting: a versatile strategy for the construction of complex supramolecular architecture. Chem. Soc. Rev. 44, 779–789 (2015).
Article CAS PubMed Google Scholar
Rama, T. et al. Integrative self-sorting of bipyridinium/diazapyrenium-based ligands into pseudo[1]rotaxanes. Chem. Eur. J. 23, 16743–16747 (2017).
Article CAS PubMed Google Scholar
Fahrenbach, A. C., Bruns, C. J., Cao, D. & Stoddart, J. F. Ground-state thermodynamics of bistable redox-active donor–acceptor mechanically interlocked molecules. Acc. Chem. Res. 45, 1581–1592 (2012).
Article CAS PubMed Google Scholar
Datta, S., Saha, M. L. & Stang, P. J. Hierarchical assemblies of supramolecular coordination complexes. Acc. Chem. Res. 51, 2047–2063 (2018).
Article CAS PubMed PubMed Central Google Scholar
Wang, A., Huang, J. & Yan, Y. Hierarchical molecular self-assemblies: construction and advantages. Soft Matter 10, 3362–3373 (2014).
Article CAS PubMed Google Scholar
Elemans, J. A. A. W., Rowan, A. E. & Nolte, R. J. M. Mastering molecular matter. Supramolecular architectures by hierarchical self-assembly. J. Mater. Chem. 13, 2661–2670 (2003).
Chen, L. J. & Yang, H. B. Construction of stimuli-responsive functional materials via hierarchical self-assembly involving coordination interactions. Acc. Chem. Res. 51, 2699–2710 (2018).
Article CAS PubMed Google Scholar
Service, R. F. How far can we push chemical self-assembly? Science 309, 95–95 (2005).
Article CAS PubMed Google Scholar
Wang, F., Liao, R. & Wang, F. Pathway control of π‐conjugated supramolecular polymers by incorporating donor‐acceptor functionality. Angew. Chem. Int. Ed. Engl. 62, e202305827 (2023).
Article CAS PubMed Google Scholar
Borsdorf, L. et al. Pathway-controlled aqueous supramolecular polymerization via solvent-dependent chain conformation effects. J. Am. Chem. Soc. 145, 8882–8895 (2023).
Article CAS PubMed Google Scholar
Leira-Iglesias, J., Sorrenti, A., Sato, A., Dunne, P. A. & Hermans, T. M. Supramolecular pathway selection of perylenediimides mediated by chemical fuels. Chem. Commun. 52, 9009–9012 (2016).
Korevaar, P. A. et al. Pathway complexity in supramolecular polymerization. Nature 481, 492–496 (2012).
Article CAS PubMed Google Scholar
Korevaar, P. A., De Greef, T. F. A. & Meijer, E. W. Pathway complexity in π-conjugated materials. Chem. Mat. 26, 576–586 (2014).
Baskakov, I. V., Legname, G., Baldwin, M. A., Prusiner, S. B. & Cohen, F. E. Pathway complexity of prion protein assembly into amyloid. J. Biol. Chem. 277, 21140–21148 (2002).
Article CAS PubMed Google Scholar
Stern, M., Jayaram, V. & Murugan, A. Shaping the topology of folding pathways in mechanical systems. Nat. Commun. 9, 4303 (2018).
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